Evidence for atomic mixing via multiple intermediates during the dynamic interconversion of silicate oligomers in solution.

نویسندگان

  • Kim E Jelfs
  • Edwin Flikkema
  • Stefan T Bromley
چکیده

We investigate Si(8)- and Si(16)-based silicate species via global optimisation searches and ab initio calculations and propose a new multi-mechanism interpretation of the experimentally observed atomic mixing of silicate oligomers in solution.

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عنوان ژورنال:
  • Chemical communications

دوره 48 1  شماره 

صفحات  -

تاریخ انتشار 2012